Antimony: (Sb)
Melting
Point:
1167
Fahrenheit
\ 631
Celsius
Boiling
Point:
2889
Fahrenheit
\ 1587
Celsius
A lustrous
grey
metalloid,
it is
found in
nature
mainly as
the
sulfide
mineral
stibnite
(Sb2S3).
Antimony
compounds
have been
known
since
ancient
times and
were used
for
cosmetics,
metallic
antimony
was also
known but
mostly
identified
as lead.
Antimony
compounds
are
prominent
additives
for
chlorine
and
bromine
containing
fire
retardants
found in
many
commercial
and
domestic
products.
The
largest
application
for
metallic
antimony
is as
alloying
material
for lead
and tin.
It
improves
the
properties
of the
alloys
which are
used as in
solders,
bullets
and ball
bearings.
An
emerging
application
is the use
of
antimony
in
microelectronics.
Alloys
Antimony
forms a
highly
useful
alloy with
lead,
increasing
its
hardness
and
mechanical
strength.
For most
of the
application
where lead
is used
varying
amounts of
antimony
are use as
alloying
metal. The
Sb–Pb
alloy is
used in
lead–acid
batteries.
It is used
in
antifriction
alloys,
such as
Babbitt
metal. It
is used as
an alloy
in bullets
and lead
shot,
cable
sheathing,
type metal
(e.g. for
linotype
printing
machines,
solder –
some
"lead-free"
solders
contain 5%
Sb, in
pewter,
and in
hardening
alloys
with low
tin
content in
the
manufacturing
of organ
pipes.
Antimony
is a
silvery,
lustrous
gray metal
that has a
Mohs scale
hardness
of 3.
Therefore,
antimony
by itself
is not
used to
make hard
objects:
coins made
of
antimony
were
issued in
China's
Guizhou
province
in 1931,
but
because of
their
rapid wear
their
minting
was
discontinued.
Antimony
is
resistant
to attack
by acids.
The
largest
application
world wide
for
antimony
is the use
as flame
retardants
with 60%
while the
use in
alloys for
batteries,
bearings
and
solders
accounts
for 20% of
the
produced
antimony.
In tiny
amounts,
antimony
is
increasingly
being used
in the
semiconductor
industry
as a
dopant for
ultra-high
conductivity
n-type
silicon
wafers in
the
production
of diodes,
infrared
detectors,
and
Hall-effect
devices.
Other
applications
include
use is in
polymers,
additive
in some
glasses as
fining
agents,
aiding in
the
removal of
microscopic
bubbles
and a
large
application
is for the
use as
pigment.
Precautions
Antimony
and many
of its
compounds
are toxic,
and the
effects of
antimony
poisoning
are
similar to
arsenic
poisoning.
The
toxicity
of
antimony
is by far
lower than
that of
arsenic,
this might
be caused
by the
significant
differences
of uptake,
metabolism
and
excretion
between
arsenic
and
antimony.
The uptake
of
antimony(III)
or
antimony(VI)
in the
gastrointestinal
tract is
at most
20%.
Antimony(VI)
is not
quantitative
reduced to
antimony(III)
in the
cell.
Methylation
of
antimony
does not
occur and
therefore
the
excretion
of
antimony(VI)
in the
urine is
the main
way of
elimination.
Reported
cases of
intoxication
by
antimony
equivalent
to 90 mg
antimony
potassium
tartrate
dissolved
from
enamel
showed
only short
term
effects.
An
intoxication
with 6 g
of
antimony
potassium
tartrate
was deadly
after 3
days.
Inhalation
of
antimony
dust is
harmful
and in
certain
cases may
be fatal;
in small
doses,
antimony
causes
headaches,
dizziness,
and
depression.
Larger
doses such
as
prolonged
skin
contact
may cause
dermatitis;
otherwise
it can
damage the
kidneys
and the
liver,
causing
violent
and
frequent
vomiting,
and will
lead to
death in a
few days.
The
abundance
of
antimony
in the
Earth's
crust is
estimated
at 0.2 to
0.5 parts
per
million,
comparable
to
thallium
at 0.5
parts per
million
and silver
at 0.07
ppm. Even
though
this
element is
not
abundant,
it is
found in
over 100
mineral
species.
Antimony
is
sometimes
found
native,
but more
frequently
it is
found in
the
sulfide
stibnite
(Sb2S3)
which is
the
predominant
ore
mineral.
Commercial
forms of
antimony
are
generally
ingots,
broken
pieces,
granules,
and cast
cake.
Other
forms are
powder,
shot, and
single
crystals.
The
People's
Republic
of China
was the
top
producer
of
antimony
with about
84% world
share
followed
at a
distance
by South
Africa,
Bolivia
and
Tajikistan.
Antimony
ingots are
currently
selling in
the 15.00 -
23.00
dollar
range per
pound.
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